Brad Pitt reportedly had an unexpected run-in with his ex-wife Angelina Jolie’s family.

The actor recently for an exhibition by his “Moneyball” director, Bennett Miller — as did Jolie’s father, Jon Voight, and brother, James Haven.

“Plenty of people noticed how awkward it was that Brad was in the same room as [Angelina’s] family, and it’s not a big space,” an eyewitness Tuesday.

“I’m told James was amicable and acknowledged Brad, but I didn’t see them talking,” the spy continued. “They were mostly stood apart for the duration of the event, speaking with friends.”

The source added that those in attendance whispered about the run-in, and it’s believed Pitt was unaware his former in-laws would be there.

The Oscar winner, 60, was accompanied by his girlfriend, , both of whom were reportedly “polite and acknowledged” Voight, 85, and Haven, 50.

Pitt looked stylish in a brown leather jacket with a fuzzy collar, which he wore atop a polo shirt, denim jeans and suede boots.

Meanwhile, the jewelry designer, 31, opted for a white tank top beneath a beige cardigan, which she paired with black leather pants and matching boots.

Also at the intimate affair was , who made sure to at the gathering.

The eyewitness said Asghari “went up and asked for a selfie with Brad, mentioning how much the singer loved him.”

The fitness trainer, 29, “then switched sides and went over and was seen chatting to James and Jon for a while,” according to the spy.

Pitt and de Ramon, who was , in November 2022.

The couple went on to a year later.

“This is Brad’s first proper relationship since the divorce. He ,” an insider told People in November 2023.

“It’s great to see him in a good place,” the informant added, noting that de Ramon makes Pitt “very happy.”

Jolie, 48, in September 2016. Though they since March 2019, their contentious custody battle rages on.

The exes — Maddox, 22, Pax, 20, Zahara, 19, Shiloh, 17, and twins Knox and Vivienne, 15 — from whom Pitt seems to be estranged.

Zahara at her college sorority’s induction ceremony in November 2023; Pax reportedly in a Father’s Day 2020 rant.

The “Once Upon a Time… in Hollywood” star has not been pictured publicly with his kids since the split, which was preceded by .

Though the actor , he did .

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Voight in April 2021 that his former son-in-law “has had some difficulties with alcohol.”

“I hope that he takes care of things, and I pray for the guy,” the “Midnight Cowboy” star added at the time. “The kids are coping as best they can.”

As for Haven, he recently to be more present for his sister’s brood.

“It started with the protection of her and her children — my nieces and nephews,” the “Monster’s Ball” star said on the “90who10” podcast earlier this month.

“I set my life up so I can be present with whatever the situation,” he continued. “I want to be there for them or for her, whatever she’s going through.”